Gerardo Adesso

Abstract The classical Gibbs paradox concerns the entropy change upon mixing two gases. Whether an observer assigns an entropy increase to the process depends on their ability to distinguish the gases. A resolution is that an `ignorant' observer, who cannot distinguish the gases, has no way of extracting work by mixing them. Moving the thought experiment into the quantum realm, we reveal new and surprising behaviour: the ignorant observer can extract work from mixing different gases, even if the gases cannot be directly distinguished. Moreover, in the macroscopic limit, the quantum case diverges from the classical ideal gas: as much work can be extracted as if the gases were fully distinguishable. We show that the ignorant observer assigns more microstates to the system than found by naive counting in semiclassical statistical mechanics. This demonstrates the importance of accounting for the level of knowledge of an observer, and its implications for genuinely quantum modifications to thermodynamics.

xtendibility of bosonic Gaussian states is a key issue in continuous-variable quantum information. We show that a bosonic Gaussian state is $k$-extendible if and only if it has a Gaussian $k$-extension, and we derive a simple semidefinite program, whose size scales linearly with the number of local modes, to efficiently decide $k$-extendibility of any given bosonic Gaussian state. When the system to be extended comprises one mode only, we provide a closed-form solution. Implications of these results for the steerability of quantum states and for the extendibility of bosonic Gaussian channels are discussed. We then derive upper bounds on the distance of a $k$-extendible bosonic Gaussian state to the set of all separable states, in terms of trace norm and R\’enyi relative entropies. These bounds, which can be seen as “Gaussian de Finetti theorems,” exhibit a universal scaling in the total number of modes, independently of the mean energy of the state. Finally, we establish an upper bound on the entanglement of formation of Gaussian $k$-extendible states, which has no analogue in the finite-dimensional setting.