Kevin Ferreira

Interacting spin systems in solids underpin a wide range of quantum technologies, from quantum sensors and single-photon sources to spin-defect-based quantum registers and processors. We develop a quantum-computer-aided framework for simulating such devices using a general electron spin resonance Hamiltonian incorporating zero-field splitting, the Zeeman effect, hyperfine interactions, dipole-dipole spin-spin terms, and electron-phonon decoherence. Within this model, we combine Gray-encoded qudit-to-qubit mappings, qubit-wise commuting aggregation, and a multi-reference selected quantum Krylov fast-forwarding (sQKFF) hybrid algorithm to access long-time dynamics while remaining compatible with NISQ and early fault-tolerant hardware constraints. Numerical simulations demonstrate the computation of autocorrelation functions up to ∼ 100 ns, together with microwave absorption spectra and the ℓ1-norm of coherence, achieving 18-30% reductions in gate counts and circuit depth for Trotterized time-evolution circuits compared to unoptimized implementations. Using the nitrogen vacancy center in diamond as a testbed, we benchmark the framework against classical simulations and identify the reference-state selection in sQKFF as the primary factor governing accuracy at fixed hardware cost. This methodology provides a flexible blueprint for using quantum computers to design, compare, and optimize solid-state spin-qubit technologies under experimentally realistic conditions.